Effective time-dependent temperature for fermionic master equations beyond the Markov and the secular approximations

Lukas Litzba, Eric Kleinherbers, Jürgen König, Ralf Schützhold, Nikodem Szpak · Physical review. B./Physical review. B · 2025

We consider a fermionic quantum system exchanging particles with an environment at a fixed temperature and study its reduced evolution by means of a Redfield-I equation with time-dependent (non-Markovian) coefficients. We find that the description can be efficiently reduced to a standard-form Redfield-II equation, however, with a obeying a universal law. At early times, after the system and environment start in a product state, the appears to be very high, yet eventually it settles down towards the true environment value. In this way, we obtain a time-local master equation, offering high accuracy at all times and preserving the crucial properties of the density matrix. It includes non-Markovian relaxation processes beyond the secular approximation and time-averaging methods and can be further applied to various types of Gorini-Kossakowski-Sudarshan-Lindblad equations. We derive the theory from first principles and discuss its application using a simple example of a single quantum dot.

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