A high-performance dysprosium single-ion magnet with local pseudo cubic geometry
Yanbo Shi, Chennan Zhang, Mingyue Shi, Yang Chun Zhou, Hong Li, Rui Liu, Shaojun Zheng, Aihua Yuan, Lei Chen, Shuyang Chen, Bing Zhu Yin, Zhao‐Bo Hu · Inorganic Chemistry Frontiers · 2024
An eight-coordinate Dy( iii ) complex with high energy barrier over 600 K represents the first case of zero-field SMM behaviour for a mononuclear cubic Ln( iii ) complex. This work provides a new avenue for available high-performance SMMs.