A MULTIMODE-LIKE SELECTION OF CENTERS OF GAUSSIAN BASIS FUNCTIONS WHEN COMPUTING VIBRATIONAL SPECTRA USING COLLOCATION
Sergei Manzhos, Tucker Carrington, Xiaogang Wang · Proceedings of the 73rd International Symposium on Molecular Spectroscopy · 2018
Detailed information on the absorption and emission spectra of satellite plume constituents is lacking. Fluorocarbons are used as a space vehicle propellant in cold gas and pulsed plasma thrusters. Consequently, these uses likely produce small fluorocarbon radicals through pyrolysis and solar driven photolysis. Specifically, it’s been shown that certain VUV wavelengths can produce electronically excited CF$_{3}$ radicals from parent fluorocarbons,\\footnote{Washida, N., Suto, M., Nagase, S., Nagashima, U., Morokuma, K., \\textit{J. Chem Phys}. 78, 1025, (1983).} but it has not been shown if ground state CF$_{3}$ radicals may be produced as well. Furthermore, the CF$_{3}$ radical’s laser induced fluorescence spectrum has never been reported. Here we investigate the photosynthesis of CF$_{3}$ radical from VUV excitation of fluorocarbons, the direct fluorescence from the CF$_{3}$ radical, and the radical’s relevance in the space environment.