Calculation and Analysis of Performances of Adsorbing Phase's Thermo-dynamics
Wang Kei-ming · Journal of Henan Normal University · 2006
Possible modes of adsorbing molecules' movement on an adsorbent's surface are analyzed,and in some cases the influence of the adsorbing molecules' oscillations perpendicular to the adsorbent's surface on its adsorbing isotherm should not be ignored.Considering the contribution by the energy of oscillation,we preliminarily make analysis and calculation of the thermo-dynamical performances of adsorbing phase,using the distribution of macro-regular matrix,thus obtaining the thermo-dynamical state and entropy in which the adsorbing phase is under the extremities of high and low temperatures,the relative fluctuation of number of the adsorbing phase′s particles and an expression for thermo-volume of the adsorbing phase.