Note: From reaction-diffusion systems to confined Brownian motion
S. Martens · The Journal of Chemical Physics · 2016
In this note, we demonstrated for the first time that one can derive an expression for the effective diffusion coefficient, equal to the Lifson-Jackson formula, using a subsequent homogenization of the 1D reaction-diffusion-advection equation. The latter has been derived by applying asymptotic perturbation analysis to the underlying 3D reaction-diffusion equation with spatially dependent no-flux boundary conditions and incorporates the effects of boundary interactions on the reactants via a boundary-induced advection term [S. Martens et al, Phys. Rev. E 91, 022902 (2015)].