Polymer size distribution and average molecular weights for reactions involving variable propagation rates

H. J. R. Maget · Journal of Polymer Science · 1962

Abstract General equations are derived to predict product distribution and number‐average molecular weight of consecutive competitive second‐order reactions, where rates of propagation are different for the m first reaction steps and become identical for all subsequent reactions. The equations have been applied to experimental results obtained for the propylene oxide—water reaction.

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