Coulometric method of the chloride ion concentration measurement: mathematical model of the measuring transducer and its experimental verification
W. Holiczer · Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE · 2001
The present paper deals with theoretical basis of coulometric method used for measurement of chloride ions concentration in water solutions. Static transfer equations were derivated for generator electrodes circuit, as well as for equation describing the kinetics of phenomena taking place in detector electrodes circuit. Basing on assumptions resulting from mathematical models, chloride ions concentration meter was designed and built. This model was used for experimental verification of derivated transfer equations. Results of performed measurements and their analysis confirmed presented theoretical considerations.