Using a Graphing Calculator to Determine a First-Order Rate Constant When the Infinity Reading Is Unknown
Deborah A. Moore-Russo, José E. Cortés-Figueroa · Journal of Chemical Education · 2002
The infinity value is an important aspect of first-order reactions that is often neglected. In fact, incorrect or missing infinity values can produce curvature of the logarithmic plot which can lead to incorrect assumptions that a reaction is not first-order. This paper uses data from the classic acid–catalyzed sucrose inversion experiment to demonstrate how to use a graphing calculator as an alternate means to determine the infinity value of the physical property being used to follow the progress of a chemical reaction and how to determine the rate constant which governs a first-order reaction when the infinity value is unknown.