Studies on A.C. Polarography. V. Theory of Reversible Wave
Mitsugi Senda, Isamu Tachi · Bulletin of the Chemical Society of Japan · 1955
Abstract The electrolytic current due to the superposition of an alternating potential upon a constant potential applied to the electrode is approximately derived for the case of reversible reaction. The parameter which determines the reversibility of the a.c. electrolysis is also given. Using the above derived results, the instateneous electrolytic current as well as current-voltage curves of reversible Breyer’s and Fournier’s polarogram are shown.